Presence of phosphorus in Nephila clavipes dragline silk

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A two-dimensional spin-diffusion NMR study on the local structure of a water-soluble model peptide for Nephila clavipes dragline silk (MaSp1) before and after spinning

INTRODUCTION The dragline silk of the golden orb web spider Nephila clavipes has received significant attention because of its remarkable mechanical properties, which include toughness and high tensile strength.1,2 This silk contains two structural proteins designated as major ampullate spidroin 1 (MaSp1) and major ampullate spidroin 2 (MaSp2).3,4 The dominant MaSp1 can be described as AB block...

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Albeit silks are fairly well understood on a molecular level, their hierarchical organisation and the full complexity of constituents in the spun fibre remain poorly defined. Here we link morphological defined structural elements in dragline silk of Nephila clavipes to their biochemical composition and physicochemical properties. Five layers of different make-ups could be distinguished. Of thes...

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ژورنال

عنوان ژورنال: Biophysical Journal

سال: 1996

ISSN: 0006-3495

DOI: 10.1016/s0006-3495(96)79594-2